Ok, so CTMinerMike and I visited Old Mine Park in Connecticut today only to stumble upon an unusual finding. By the adit (Which is filled) there is a large vein of exposed marcasite wit some overhanging rock protecting the ground from intense saturation from the rain. There were dull to intense yellow crytalline crusts of Sulfates on the altered surface of the vein and We couldn't help to take a look. I had no idea what it was, so I grabbed the best pieces I could find and entered the description on Mindat after looking at it under the microscope.
It took me a while to narrow the results down, there were quite a few phosphates with close resemblance but it occured in a sulfurous environment, so I highly doubted that it was a phosphate.
Ferricopiapite is formed by the action of water on Marcasite and Limonite
3FeS2+2FeOOH+24H2O===E===> Fe+++5(SO4)6O(OH)*20H20
It is simple for this compound to form, 3 moles Ferric iron(II) is ionized by light or heat forming a total of 5 Ferrous iron to combine. Sulfur combines with oxygen and hydrogen to become H2SO4, 6 moles which passes over the fully ionized iron compounds and replacement occurs, 3 moles of hydrogen bonds with oxygen and forms water of crystallization that is part of Ferricopiapite's structure. Neat stuff if you're a chem geek like me!!!
_________________ OK kids, let's get this straight, When I talk about rocks, I'm not talking about THOSE types of rocks....
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